A new approach to scratch resistance

17 Aug 2011

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A new way to analyse how coatings of tiny particles alter the properties of transparent plastic could help researchers create lightweight windows with nearly the strength of glass.

 
Meng Qu, a postdoc in the Department of Materials Science and Engineering (DMSE), was the lead author of the paper on improving scratch resistance. Photo: Dominick Reuter

The same method could also lead to high-strength, scratch-resistant coatings that could be applied to many different materials, according to the MIT researchers who developed the analysis.

The analysis used a polymer called poly(methyl methacrylate), or PMMA, which is widely used as a glass substitute. Known generically as acrylic, and sold under trademarks such as Lucite or Plexiglas, this material can be brittle and is far less resistant to scratching than glass.

Other researchers have added silica particles measuring just nanometres across to PMMA, creating a polymer-particle nanocomposite with much greater strength. But the MIT team, for the first time, has found a way to analyse the particle-polymer interactions of such coatings at the nanoscale, which could facilitate the discovery of improved coatings.

Their work was reported in July in the journal Soft Matter.

The analysis was carried out by Meng Qu, a postdoc in MIT's Department of Materials Science and Engineering, along with Associate Professor of Materials Science and Engineering Krystyn Van Vliet and several researchers at DuPont Nanocomposite Technologies in Delaware. The work was partly funded by the DuPont-MIT Alliance.

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