Breakthrough in battery technology – no recharging needed!

19 Nov 2013

1

Researchers at Stanford University might have made an advance in battery technology that could potentially make oil-based car fuels redundant; and virtually eliminate the need to recharge the cells in your mobile phone or other devices.

The scientists from the university and the US Department of Energy's SLAC National Accelerator Laboratory have developed a battery electrode that can heal itself, potentially offering a commercially viable path for making the next generation of lithium-ion batteries.

Research from Chao Wang at Stanford University, California, and Hui Wu of Tsinghua University, Beijing, led to the realisation that by deliberately breaking certain bonds, the chemical bonds would be attracted back.

You won't be able to physically smash them to pieces then watch them reform before your eyes, but inside the new batteries, something very similar happens.

This is a result of the techniques developed in chasing larger power packs, increasing the energy density while allowing retention of the same form factor that we are all used to.

One of these techniques has been to incorporate silicon into the cathode. This allows more energy, but leads to an unusable battery after a few discharge cycles.

Silicon is prone to cracking, as it expands when packed with electrons to increase power. Once cracked, the broken silicon is unable to hold charge. This has been remedied with a newly developed polymer coating.

According to scientists, the secret behind the newly invented battery is a stretchy polymer that coats the electrode, binds it together and automatically heals small cracks that develop while the battery is in use.

"Self-healing is very important for the survival and long lifetimes of animals and plants," Chao Wang, a postdoctoral researcher at Stanford and one of two principal authors of the paper, said in a statement. "We want to incorporate this feature into lithium-ion batteries so they will have a long lifetime as well."

For the project, Chao added tiny nanoparticles of carbon to the polymer so it would conduct electricity.

"We found that silicon electrodes lasted 10 times longer when coated with the self-healing polymer, which repaired any cracks within just a few hours," Zhenan Bao, a Stanford professor, said in a statement.

The new battery electrodes currently work for about 100 charge-discharge cycles without significantly losing their energy-storage capacity. However, scientists are aiming to enhance the capability to about 500 cycles for cell phones and up to 3,000 cycles for an electric vehicle.

According to scientists, one of the most promising electrode materials is silicon, which can soak up lithium ions from the battery fluid during charging, and then release them when the battery is put to work. However, silicon electrodes expand to three times their normal size and shrink back down again each time the battery charges and discharges, leading the material to crack soon and diminish the battery's performance.

''To make the self-healing coating, scientists deliberately weakened some of the chemical bonds within polymers – long, chain-like molecules with many identical units,'' a Stanford University statement read.

''The resulting material breaks easily, but the broken ends are chemically drawn to each other and quickly link up again, mimicking the process that allows biological molecules such as DNA to assemble, rearrange and break down.''

A research paper related to the project was published online on Nature Chemistry on Sunday.

(Read More: Scientists invent self-healing battery electrode)

Business History Videos

History of hovercraft Part 3...

Today I shall talk a bit more about the military plans for ...

By Kiron Kasbekar | Presenter: Kiron Kasbekar

History of hovercraft Part 2...

In this episode of our history of hovercraft, we shall exam...

By Kiron Kasbekar | Presenter: Kiron Kasbekar

History of Hovercraft Part 1...

If you’ve been a James Bond movie fan, you may recall seein...

By Kiron Kasbekar | Presenter: Kiron Kasbekar

History of Trams in India | ...

The video I am presenting to you is based on a script writt...

By Aniket Gupta | Presenter: Sheetal Gaikwad

view more