How to clean up oil spills

By By Larry Hardesty, MIT News Office | 12 Sep 2012

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MIT researchers have developed a new technique for magnetically separating oil and water that could be used to clean up oil spills. They believe that, with their technique, the oil could be recovered for use, offsetting much of the cost of cleanup.

The researchers will present their work at the International Conference on Magnetic Fluids in January. Shahriar Khushrushahi, a postdoc in MIT's department of electrical engineering and computer science, is lead author on the paper, joined by Markus Zahn, the Thomas and Gerd Perkins Professor of Electrical Engineering, and T. Alan Hatton, the Ralph Landau Professor of Chemical Engineering. The team has also filed two patents on its work.

In the MIT researchers' scheme, water-repellent ferrous nanoparticles would be mixed with the oil, which could then be separated from the water using magnets. The researchers envision that the process would take place aboard an oil-recovery vessel, to prevent the nanoparticles from contaminating the environment. Afterward, the nanoparticles could be magnetically removed from the oil and reused.

According to Zahn, there's a good deal of previous research on separating water and so-called ferrofluids - fluids with magnetic nanoparticles suspended in them. Typically, these involve pumping a water-and-ferrofluid mixture through a channel, while magnets outside the channel direct the flow of the ferrofluid, perhaps diverting it down a side channel or pulling it through a perforated wall.

This approach can work if the concentration of the ferrofluid is known in advance and remains constant. But in water contaminated by an oil spill, the concentration can vary widely. Suppose that the separation system consists of a branching channel with magnets along one side. If the oil concentration were zero, the water would naturally flow down both branches. By the same token, if the oil concentration is low, a lot of the water will end up flowing down the branch intended for the oil; if the oil concentration is high, a lot of the oil will end up flowing down the branch intended for the water.

Orthogonal thinking

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